Pi Centauri, Latinized from π Centauri, is a binary star system in the southern constellation of Centaurus. It has a blue-white hue and is visible to the naked eye with a combined apparent visual magnitude of +3.90.[ The system is located at a distance of approximately 360 from the Sun based on stellar parallax,] and is drifting further away with a radial velocity of around +9 km/s.[ It is a member of the Lower Centaurus–Crux subgroup of the Scorpius–Centaurus association.][
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The magnitude +4.08[ primary, designated component A, is a B-type main-sequence star with a stellar classification of B5Vn,][ where the 'n' suffix indicates broad, diffuse (nebulous) absorption line due to rapid rotation. This star is spinning with a projected rotational velocity of 340 km/s, giving it an equatorial bulge that is 22% larger than the polar radius.][ It has 6.4] times the mass of the Sun and is radiating 783[ times the Sun's luminosity from its photosphere at an effective temperature of 16,760 K.][
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The secondary companion, component B, is magnitude +5.65[ with a class of B6V][ and 3.7] times the Sun's mass. The pair orbit around their common barycentre once every 39 years with an eccentricity of 0.8530. The semi-major axis of the companion is 0.23 at an inclination of 19.4°.